Chromium trioxide solution in sulfuric acid - Names and Identifiers
Chromium trioxide solution in sulfuric acid - Physico-chemical Properties
| Molecular Formula | CrO3
|
| Molar Mass | 99.9943 |
| Density | 1.298 g/mL at 25 °C |
| Storage Condition | -20°C |
| Use | Introduction Jones reagent, also known as Jones reagent, is a reagent for selective oxidation of organic compounds. It can oxidize secondary alcohols into corresponding ketones without affecting the double or triple bonds in the molecule; it can also oxidize allyl alcohol (primary alcohol) into aldehydes. Generally, secondary alcohol or allyl alcohol is dissolved in acetone or dioxymethane, and then the reagent is dropped for oxidation reaction. The reaction is generally carried out below room temperature. |
Chromium trioxide solution in sulfuric acid - Risk and Safety
| Risk Codes | R36/37/38 - Irritating to eyes, respiratory system and skin.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R48/20 -
R42/43 - May cause sensitization by inhalation and skin contact.
R35 - Causes severe burns
R23/24 -
R61 - May cause harm to the unborn child
R60 - May impair fertility
R46 - May cause heritable genetic damage
R45 - May cause cancer
R62 - Possible risk of impaired fertility
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R48/23 -
R26 - Very Toxic by inhalation
R21/22 - Harmful in contact with skin and if swallowed.
R9 - Explosive when mixed with combustible material
|
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S23 - Do not breathe vapour.
S53 - Avoid exposure - obtain special instructions before use.
S28 - After contact with skin, wash immediately with plenty of soap-suds.
|
| UN IDs | UN 3098 5.1(8) / PGII |
| WGK Germany | 3 |
Chromium trioxide solution in sulfuric acid - Introduction
EDTA methidium propylamide(EDTA methidium propylamide), also known as methyl bromide EDTA methidium propylamide, is an organic compound. The following is a description of the nature, use, formulation and safety information of EDTA methidiumpropylamide:
Nature:
EDTA methidiumpropylamide is a colorless or pale yellow crystal, soluble in water and organic solvents. Its chemical structure contains EDTA (ethylenediaminetetraacetic acid) and methyl groups.
Use:
EDTA methidiumpropylamide is mainly used for oxidation reactions in organic synthesis. It can oxidize an alcohol, aldehyde or ketone to the corresponding carboxylic acid. In addition, EDTA methidiumpropylamide can also be used to identify whether chemical substances contain double bonds or oxygen-containing functional groups.
Method:
The method for preparing EDTA methidiumpropylamide is to react EDTA with trimethylamine bromide under alkaline conditions, and obtain the final product through extraction and crystallization.
Safety Information:
EDTA methidiumpropylamide needs to be handled carefully because it is an oxidant and has certain toxicity. Avoid contact with combustibles, reducing agents or inflammables during use, and avoid inhalation or skin contact. Wear appropriate protective equipment, such as chemical protective gloves and goggles. At the same time, EDTA methidium propylamide should be stored in sealed containers, away from ignition and heat sources. When disposing of waste, it is necessary to dispose of it in accordance with local regulations. Before using EDTA methidium propylamide, it is recommended to consult the relevant safety data sheets and operating manuals and to comply with the relevant laboratory safety regulations.
Last Update：2024-04-09 21:11:58